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Topically, glycerin does several things at once: Your skin makes glycerin on its own (mostly from sebaceous oil breakdown) and shuttles it to your outermost layer of skin, or your epidermis, via aquaporin-3
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AHK-Cu emerged later as researchers explored variations on the original copper-binding tripeptide structure, swapping the glycine residue for alanine to see how the change affected biological activity
Think of injections as intensive treatment phases and topical application as maintenance between cycles
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