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Glutathione works on skin pigment production mainly by inhibiting tyrosinase, one of the enzymes involved in making melanin

For glutamine tracing, 4 mM of U- 13 C-glutamine was added to the glutamine-free RPMI-1640 medium with 10% v/v HI-FBS, 1 mM HEPES, and 1 mM sodium pyruvate

47 Taken together, these data suggest the reduced GSH/GSSG antioxidant capacity is insufficient to counter excessive OH production, and that unopposed OH can reach the nucleus to create the oxidative DNA adduct, 8-oxo-dG

doi: 10.1007/s00011-015-0874-1 23 MosserDMEdwardsJP