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Consoli A, Formoso G, Baldassarre MPA, et al
The cyclic lactam constraint between the Asp and Lys side chains preorganizes the conserved His-Phe-Arg-Trp (HFRW) message tetrapeptide of -MSH into the receptor-bound conformation, which is responsible for the dramatic potency increase relative to the linear native hormone
ValentineGWMasonGFGomezRFasulaMWatzlJPittmanBet al
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