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Its guanidinium sidechain can form a hydrogen bond to the sulfur of glutathione, thereby lowering the pK a value of the thiol group, and mutation of Arg15 to Ala or His decreases the steroid isomerase activity by two orders of magnitude, twice the effect of the Tyr9Phe mutation (Bjrnestedt et al., 1995a)

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Thats where these injections come in glutathione is a powerful antioxidant naturally produced in the liver